Premium Ammonium Polyphosphate (APP): High - Performance Multifunctional Chemical Raw Material
Core Properties and Fundamental Characteristics
Chemical Composition: APP contains 30% - 32% phosphorus and 14% - 16% nitrogen. This nitrogen - phosphorus combination makes it critical in multiple applications, such as providing essential nutrients for plant growth in fertilizers and achieving efficient flame retardancy through the synergistic effect of phosphorus and nitrogen in flame - retardant scenarios.
Thermal Stability: With a thermal decomposition temperature of ≥280°C, APP remains stable in high - temperature environments. This property makes it suitable for manufacturing heat - resistant products like engineering plastics and fireproof coatings used in high - temperature conditions.
Physical Form and Solubility: The degree of polymerization affects its water solubility. When n is 10 - 20, it is water - soluble; when n > 20, it is poorly soluble. Common high - polymer products (n>1000) are nearly insoluble in water, existing as white flowable powders with a bulk density of approximately 0.7g/cm³, a density of about 1.9g/cm³, a pH in the near - neutral range of 5.5 - 7.0, and a moisture content of ≤0.25%.
Major Application Fields
Flame Retardant Field: The Core of Halogen - Free Flame Retardants
APP is a vital halogen - free phosphorus - based flame retardant, becoming increasingly prominent in the development trend of environmentally friendly and low - toxicity flame - retardant materials.
Intumescent Fireproof Coatings: Widely used in the formulations of intumescent fireproof coatings. When a fire occurs, APP decomposes upon heating, prompting the coating to expand and form a porous foamy carbonaceous layer. This carbonaceous layer acts as a thermal insulation barrier, effectively blocking heat transfer to the substrate and slowing down the temperature rise of the substrate, thus gaining time for personnel evacuation and fire fighting. In scenarios with extremely high fire safety requirements, such as high - rise buildings, power facilities, and ships, these coatings play a key fire protection role due to the function of APP.
Plastics and Rubber Products: Adding APP to thermoplastic plastics like polyethylene and polypropylene, as well as rubber products, can significantly improve the flame retardancy of materials. In plastic casings of electronic and electrical products, automotive interior plastic parts, and insulating rubber of wires and cables, APP inhibits the continuation of combustion by forming a stable carbon layer on the material surface through the condensed - phase flame retardancy mechanism, meeting the strict flame retardant standards of relevant industries and ensuring product safety in use.
Fibers and Fabrics: Used for the flame retardant treatment of fibers and fabrics. After treatment with APP, fibers and fabrics are not easy to burn when encountering a fire source, reducing the risk of large - area fire spread caused by textiles in a fire. It is often used in products such as workwear fabrics, curtains, and carpets to improve the fire safety of public places and household textiles.
Fertilizer Industry: Efficient and Multifunctional Nutrient Carrier
Key Raw Material for Water - Soluble Fertilizers: It is a key raw material for the development of water - soluble fertilizers. Especially low - polymer APP, with its good solubility, compatibility, and low crystallization temperature, becomes an ideal component of liquid fertilizers. It can be used to prepare liquid fertilizers with high phosphorus content, and its near - neutral pH makes it highly safe for crops. It can chelate metal ions such as calcium, magnesium, iron, and zinc, preventing these ions from forming precipitates in the fertilizer solution and improving the stability of the fertilizer. At the same time, it enhances the mobility of phosphorus and trace elements in the soil, making them more easily absorbed and utilized by crops, realizing the multifunctionality of fertilizers and meeting the nutrient needs of crops at different growth stages.
Long - Acting Slow - Release Characteristics: In the soil, APP gradually hydrolyzes into orthophosphate, slowly releasing phosphorus elements to provide long - term nutrient supply for crops. Compared with ordinary phosphate fertilizers, it has a longer fertilizer efficiency duration, reduces the number of fertilizations, improves the utilization rate of fertilizers, reduces agricultural production costs, and at the same time reduces soil nutrient loss and environmental pollution caused by frequent fertilization, in line with the concept of agricultural sustainable development.
Other Industrial Applications
Water Treatment Field: As a water treatment agent, APP can coordinate with hardness ions (such as calcium and magnesium ions) in water to form insoluble complexes, reducing water hardness and preventing scaling in pipelines and equipment. It can also form a protective film on the surface of metal pipelines, playing a corrosion inhibition role and suppressing metal corrosion, thus prolonging the service life of pipelines and equipment. It is widely used in industrial circulating water systems, boiler water treatment, and other scenarios.
Coating Additives: In the coating system, APP can act as a preservative, bactericide, and defoamer. It can enhance the adhesion of the coating to the substrate, making the coating adhere more firmly to the object surface. It can improve the strength of the coating, enhancing the wear - resistance and scratch - resistance of the coating. It can also improve the fluidity and leveling of the coating, making the coating surface smoother and more uniform, and improving the overall quality and decorative effect of the coating.
Specifications
| Product Name | Ammonium Polyphosphate | |||||||||
| Chemical Formula | (NH₄PO₃)ₙ | |||||||||
| Appearance | White crystalline powder | |||||||||
| CAS NO | 68333-79-9 | |||||||||
| HS Code | 31053000 | |||||||||
| EINECS NO | 271-839-7 | |||||||||
| Application | Flame retardant for plastics, rubber, coatings, textiles; | |||||||||
Quality Control Sheet
| Product Name | Ammonium Polyphosphate | ||||||
| Inspection Items | Standard | Result | |||||
| Appearance | White Powder | White Powder | |||||
| PO, (%) w/w | ≥71 | 72.09 | |||||
| N (%) w/w | ≥14 | 14.36 | |||||
| Solubility g/100ml H0,25°C | ≤0.5 | 0.318 | |||||
| pHl value (10% aqueous) | 5.5-7.5 | 6.83 | |||||
| Viscosity (100% aqueous,25°C) | ------ | 45 | |||||
| Moisture (%) w/w | ≤0.25 | 0.14 | |||||
| Average Particle Size (μm) | ≤20 | 13.36 | |||||
| Average degree of polymerization | ≥1000 | 1500 | |||||
Quality Control and Compliance Standards
Production Process and Quality: There are various methods for preparing APP. For example, the precipitation method involves dropping a certain amount of phosphoric acid into an ammonium water solution and then adding ammonium bicarbonate for reaction to generate APP. This method has a high yield and is easy to operate. The polymerization method uses polyphosphoric acid or its lactam to synthesize with monomers such as acrylic acid to obtain products with better performance. The production process strictly follows the quality control system to ensure the stability of key indicators such as product purity, degree of polymerization, and moisture content, meeting the high standards of different industries.
Compliance: The product complies with relevant industry standards and regulations. In flame retardant applications, it meets 阻燃 standards such as UL 94. In fertilizer applications, it complies with national fertilizer quality standards to ensure safe and effective use. From raw material procurement to product delivery, strict testing is carried out throughout the process to ensure that each batch of products is reliable in quality and stable in performance.
Why Choose Our Ammonium Polyphosphate?
Whether you are engaged in the manufacturing of flame - retardant materials to protect life and property safety, focused on fertilizer research and development to help agricultural harvests, or exploring innovations in other industrial fields, our APP is your reliable choice. We provide comprehensive technical support to assist customers in optimizing product formulations and solving application problems. With a wide - coverage supply chain system, we ensure the timely and stable supply of products to meet your production needs of different scales.
Unlock new possibilities for material performance improvement and function expansion with premium Ammonium Polyphosphate, and stand at the forefront of innovation and development in various industries.








